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Settings->Configure-.New

Select Jabber

On the first tab enter your account name with the @gmail.com at the end. So myname@gmail.com

On the second tab enter the following:

[x] Use protocol encryption (SSL)
[x] Allow plain-text password authentication
[x] Override default server information
Server: [talk.google.com] Port: [5223]

And that’s it!

Google Talk can be downloaded from: http://www.google.com/talk/